柯志聪;胡丽姗;俞颖华;陈建新;余友谊;张治纯;

• 1:福建师范大学化学与材料学院

摘要(Abstract)：

合成含2-氨基苯基二苯基膦水杨醛配体(三啮P^N^O配体)的3个后过渡金属镍配合物催化剂;采用元素分析、红外光谱和单晶衍射实验等方法对配合物的结构进行表征;研究了配合物对降冰片烯聚合的催化活性和影响因素.实验表明,在以甲基铝氧烷(MAO)为助催化剂时,配合物对降冰片烯聚合显示出良好的催化活性;聚合产物呈现良好的热稳定性和较为粗糙的表面形态.

关键词(KeyWords)： 聚烯烃;三啮;水杨醛;后过渡金属;镍;降冰片烯;甲基铝氧烷

Abstract:

Keywords:

基金项目(Foundation): 教育部科学技术研究重点项目(208066);; 福建省自然科学基金资助项目(2010J01026);; 福建省教育厅重点项目(JA07029);; 结构化学国家重点实验室资助项目(20080053)

作者(Authors): 柯志聪;胡丽姗;俞颖华;陈建新;余友谊;张治纯;

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