CdS空心微球的制备及其在可见光催化合成低聚壳聚糖中的应用Preparation and Visible-light Photocatalysis Application in Synthesizing Low Molecular Weight Chitosan of CdS Hollow Microsphere
王琼生;王世铭;
摘要(Abstract):
以天然高分子壳聚糖为软模板,采用水热方法制备了纳米CdS空心微球,合成产物采用XRD,TEM,DRS等手段进行了表征.将合成的纳米CdS空心微球作为光催化剂,应用于可见光光催化制备低相对分子质量的壳聚糖的实验中.考察了光催化剂用量、壳聚糖浓度及反应气氛等因素对光催化氧化降解反应的影响,推测了CdS可见光催化制备低聚壳聚糖的机理.结果表明:可见光催化为低相对分子质量壳聚糖的可控制备提供了一条有效新途径.
关键词(KeyWords): 壳聚糖模板;CdS空心微球;可见光催化;壳聚糖
基金项目(Foundation): 福建省自然科学基金资助项目(2006J0251/U0650007Z0513009);; 福建省教育厅资助项目(JB05313)
作者(Authors): 王琼生;王世铭;
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