[Co(ptma)(amp)Cl][ZnCl_4]体系配合物异构体的合成及分离Synthesis and Separation of Isomers in[Co(ptma)(amp)Cl][ZnCl_4]
林榕光,马培华,罗绪强,温祖标,陶朱,张建新
摘要(Abstract)：
用过氧化物法合成了 [Co( ptma) ( amp) Cl][Zn Cl4]体系的异构体混合物 ( ptma=N-( 2 -吡啶基甲基 )丙二胺 ,amp=2 -(氨基甲基 )吡啶 ) ,并通过 Dowex( H+ )阳离子交换柱分离得到 4带配合物 ,将配合物用H2 Zn Cl4结晶 .1 3 C及1 H NMR检测表明 ,其中第二带、第四带是标题体系中的异构体且配合物阳离子中可能具有 C— H…π结构 .
关键词(KeyWords)： 钴(Ⅲ)配合物;C—H…π结构;13C和1HNMR
基金项目(Foundation):
作者(Author): 林榕光,马培华,罗绪强,温祖标,陶朱,张建新
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