阳离子聚丙烯酰胺-羧甲基纤维素电解质膜的制备及应用Preparation and Application of Cation Polyacrylamide-Carboxymethylcellulose Polyelectrolyte Membrane
黄丽珠;黄雪红;陈日耀;郑曦;陈震;
摘要(Abstract)：
以Fe3+为交联剂,制备了阳离子聚丙烯酰胺(CPAM)-羧甲基纤维素(CMC)聚合物电解质膜.用红外光谱和扫描电镜对其成分与形态进行了表征,并将其应用于电解制备高铁酸盐.实验结果表明,CPAM-CMC聚合物电解质膜能有效地阻止FeO42-向阴极室扩散,同时阴极室中生成的OH-及时地补充了阳极室中OH-的消耗.
关键词(KeyWords)： 膜;阳离子聚丙烯酰胺;羧甲基纤维素;电生成高铁酸盐
基金项目(Foundation): 福建省自然科学基金资助项目(A9910009);; 福建省科技厅基金资助项目(JB05314)
作者(Authors): 黄丽珠;黄雪红;陈日耀;郑曦;陈震;
参考文献(References)：
- [1]夏庆余,陈日耀,陈震.电解制备高铁酸盐中负脉冲作用和高铁酸盐对十二烷基苯磺酸钠的降解[J].应用化学,2005,22(1):35-39.
- [2]Sharma V K,Smith J O,Millero F J.Ferrate()oxidation of hydrogen sulfide[J].Environ Sci Technol,1997,31:2 486-2 490.
- [3]林智虹,郑晓虹,陈日耀,等.SPE阴离子交换膜技术电解制备FeO42-及其降解脱色性能的研究[J].无机化学学报,2002,18(2):214-218.
- [4]Hazel B,Roy O,Roy G,et al.Formaldehydeasa pretreatment for dermal collagen heterografts[J].BiochemicaletBiophysica Acta,1980,632:589-597.
- [5]Huang R Y M,Pal R,Moon G T.Characteristics of sodium alginate membranes for the pervaporation dehydrationof ethanol-water and isopropanol-water mixtures[J].J Membr Sci,1999,160:101-113.
- [6]Lee S H.Preparation and evaluation of crosslinked polyelectrolyte complex membrane[J].J Polym,2000,32(9):716-721.
- [7]王雅琼,许文林.聚丙烯酰胺的N-羟甲基化及氨基化[J].精细石油化工,2002(5):17-19.
- [8]Smith T J.Calcium alginate hydrogelasa matrix for enteric delivery of nucleic acids[J].Biopharm,1994,4:54-55.
- [9]Zhang L N,Zhou D,Wang H,et al.Ion exchange membranes blended by cellulose cuoxam with alginate[J].JMembr Sci,1997,124:195-201.