陈荣国;孟东伟;肖荔人;李丹;姜明;钱庆荣;陈庆华;

• 1:福建工程学院生态环境与城市建设学院
• 2:福建师范大学环境科学与工程学院

摘要(Abstract)：

以三聚氯氰(CYC)、二乙醇胺(DEA)和伯胺为反应剂,分步考察碱催化剂、反应时间等对胺亲核取代嗪氯反应结果的影响,并在此基础上合成了一系列的多元羟烷胺基-1,3,5-三嗪(3a,3b,3c),其结构均经元素分析、FTIR、1H NMR和ESI-MS表征。结果表明,CYC第一、二、三氯的取代反应,宜分别选二乙醇胺、三乙胺和碳酸氢钠作碱催化剂,并依次在-1⁵℃、455℃、45⁵0℃和8550℃和85⁹0℃下反应2 h、7 h和16 h;所得多元羟烷胺基-1,3,5-三嗪具有双亲性.

关键词(KeyWords)： 双亲;羟烷胺基-1,3,5-三嗪;亲核取代;合成

Abstract:

Keywords:

基金项目(Foundation): 福建省教育厅科技计划项目(JA12236);; 福建省自然科学基金资助项目(2011J01287)

作者(Authors): 陈荣国;孟东伟;肖荔人;李丹;姜明;钱庆荣;陈庆华;

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