不同热解温度对生物质炭8种元素含量的影响Influence of Different Pyrolysis Temperatures on Eight Elements Content of Biochar
孙小飞;陈智伟;李宇轩;马红亮;高人;尹云锋;
摘要(Abstract):
以水稻秸秆为原材料,研究不同热解温度(350,450,550,650,750℃)对生物质炭的产率、pH值和8种元素含量以及挥发特性的影响.结果表明:当热解温度由350℃上升至750℃时,生物质炭pH值介于9. 54~10. 90之间,并呈现先升高再下降的趋势;产率由43. 7%下降至31. 2%;全碳(TC)和全氮(TN)的含量分别从433. 72 g·kg-1和12. 53 g·kg-1下降至355. 37 g·kg-1和4. 34 g·kg-1,而全磷(TP)、全钾(TK)、铜(Cu2+)和钼(Mo2+)的含量则表现为升高,锌(Zn2+)和锰(Mn2+)含量与pH值变化趋势相近.在热解过程中TC和TN挥发最多,而TK和Cu2+则表现为富集.回归分析发现,热解温度与生物质炭pH、产率和元素含量(Zn2+除外)均呈极显著线性关系(P <0. 01).
关键词(KeyWords): 生物质炭;水稻秸秆;热解温度;元素含量
基金项目(Foundation): 国家自然科学基金资助项目(31470628);; 教育部科学技术研究资助项目(213019A)
作者(Authors): 孙小飞;陈智伟;李宇轩;马红亮;高人;尹云锋;
参考文献(References):
- [1]YANG Y N,SHENG G Y.Enhanced pesticide sorption by soils containing particulate matter from crop residue burns[J].Environmental Science and Technology,2003,37(16):3635-3639.
- [2]姚红宇,唐光木,葛春辉,等.炭化温度和时间与棉杆炭特性及元素组成的相关关系[J].农业工程学报,2013,29(7):199-206.
- [3]LEHMANN J,RILLIG M C,THIES J,et al.Biochar effects on soil biota-a review[J].Soil Biology and Biochemistry,2011,43(9):1812-1836.
- [4]XU Z,WANG J W,WANG S Q,et al.Successive straw biochar application as a strategy to sequester carbon and improve fertility:a pot experiment with two rice/wheat rotations in paddy soil[J].Plant and Soil,2014,378(1/2):279-294.
- [5]TENDER C A D,DEBODE J,VANDECASTEELE B,et al.Biological,physicochemical and plant health responses in lettuce and strawberry in soil or peat amended with biochar[J].Applied Soil Ecology,2016,107:1-12.
- [6]SPOKAS K A,CANTRELL K B,NOVAK J M,et al.Biochar:a synthesis of its agronomic impact beyond carbon sequestration[J].Journal of Environmental Quality,2012,41(4):973-989.
- [7]谢祖彬,刘琦,许燕萍,等.生物炭研究进展及其研究方向[J].土壤,2011,43(6):857-861.
- [8]HOSSAIN M K,STREZOV V,CHAN K Y,et al.Influence of pyrolysis temperature on production and nutrient properties of wastewater sludge biochar[J].Journal of Environmental Management,2011,92(1):223-228.
- [9]EUROPEAN BIOCHAR FOUNDATION(EBF).European biochar certificate(EBC)-version 6.5E:Guidelines for a sustainable production of biochar[EB/OL].(2018-08-30).http://www.europeanbiochar.org/en/download.DOI:10.13140/RG.2.1.4658-7043.
- [10]DAUD W M A W,ALI W S W,SULAIMAN M Z.Effect of carbonization temperature on the yield and porosity of char produced from palm shell[J].Journal of Chemical Technology and Biotechnology,2001,76(12):1281-1285.
- [11]简敏菲,高凯芳,余厚平.不同裂解温度对水稻秸秆制备生物炭及其特性的影响[J].环境科学学报,2016,36(5):1757-1765.
- [12]叶协锋,周涵君,于晓娜,等.热解温度对玉米秸秆炭产率及理化特性的影响[J].植物营养与肥料学报,2017,23(5):1268-1275.
- [13]WU W X,YANG M,FENG Q B,et al.Chemical characterization of rice straw-derived biochar for soil amendment[J].Biomass and Bioenergy,2012,47(4):268-276.
- [14]HUFF M D,KUMAR S,LEE J W.Comparative analysis of pinewood,peanut shell,and bamboo biomass derived biochars produced via hydrothermal conversion and pyrolysis[J].Journal of Environmental Management,2014,146:303-308.
- [15]RONSSE F,VAN-HECKE S,DICKINSON D,et al.Production and characterization of slow pyrolysis biochar:influence of feedstock type and pyrolysis conditions[J].Global Change Biology Bioenergy,2013,5(2):104-115.
- [16]袁金华,徐仁扣.生物质炭的性质及其对土壤环境功能影响的研究进展[J].生态环境学报,2011,20(4):779-785.
- [17]OGUNTUNDE P G,FOSU M,AJAYI A E,et al.Effects of charcoal production on maize yield,chemical properties and texture of soil[J].Biology and Fertility of Soils,2004,39(4):295-299.
- [18]LIANG C F,GASCO G,FU S L,et al.Biochar from pruning residues as a soil amendment:effects of pyrolysis temperature and particle size[J].Soil and Tillage Research,2016,164:3-10.
- [19]CAO X D,HARRIS W.Properties of dairy-manure-derived biochar pertinent to its potential use in remediation[J].Bioresource Technology,2010,101(14):5222-5228.
- [20]BAGREEV A,BANDOSZ T J,LOCKE D C.Pore structure and surface chemistry of adsorbents obtained by pyrolysis of sewage sludge-derived fertilizer[J].Carbon,2001,39(13):1971-1979.
- [21]刘燕萍.黑碳添加对土壤有机碳分解的影响[D].福州:福建师范大学,2011.
- [22]ZHENG H,WANG Z Y,DENG X,et al.Characteristics and nutrient values of biochars produced from giant reed at different temperatures[J].Bioresource Technology,2013,130(2):463-471.
- [23]CANTRELL K B,HUNT P G,UCHIMIYA M,et al.Impact of pyrolysis temperature and manure source on physicochemical characteristics of biochar[J].Bioresource Technology,2012,107(2):419-428.
- [24]卢欢亮,叶向东,汪永红,等.热解温度对污泥生物炭的表面特性及重金属安全性的影响[J].环境工程学报,2015,9(3):1433-1439.
- [25]王煌平,张青,李昱,等.热解温度对畜禽粪便生物炭产率及理化特性的影响[J].农业环境科学学报,2015,34(11):2208-2214.
- [26]项剑桥,戴光忠,吴冬妹,等.湖北宣恩县土壤全量微量元素与有机碳和p H的关系分析---以晓关侗族乡为例[J].西南农业学报,2017,30(8):1849-1853.