8-羟基喹啉与醋酸铜固相配位反应的热化学研究Studies on Thermochemistry of Solid State Coordination Reaction of 8 Hoxine with Copper Acetate
温德才,朱则善
摘要(Abstract):
用自行研制的具有恒定温度环境的反应热量计, 以6 m ol·L- 1 HCl溶液为量热溶剂, 测得8羟基喹啉与醋酸铜固相配位反应焓ΔrH○m 为- 7834±0074 kJ·m ol- 1, 从而计算得出配合物Cu(oxin)2的标准生成焓ΔfH○m 为- 114071±0074 kJ·m ol
关键词(KeyWords): 固相配位化学;热化学;8-羟基喹啉;醋酸铜
基金项目(Foundation):
作者(Author): 温德才,朱则善
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