王金娟;裴学海;杨志翔;王文琛;尹晓刚;陈治明;

• 1:贵州师范大学化学与材料科学学院贵州省功能材料化学重点实验室

摘要(Abstract)：

探讨了环境友好和无毒性的轴手性多活性中心的BINOL酰胺催化的芳香醛、乙酰丙酮及碳酸氢铵的Hantzsch反应.研究表明,在回流条件下,CH_2Cl_2中,在0.075 mmol轴手性多活性中心BINOL酰胺存在下,芳香醛、乙酰丙酮及碳酸氢铵能有效进行Hantzsch反应,高产率生成Hantzsch酯.产物通过红外、核磁、熔点进行表征.该方法与现有合成方法相比,具有操作简便、收率高、用时短等优点,有潜在的应用前景.

关键词(KeyWords)： BINOL酰胺;合成;Hantzsch反应;Hantzsch酯

Abstract:

Keywords:

基金项目(Foundation): 贵州师范大学研究生创新基金资助项目(研创201621);; 国家自然科学基金资助项目(21362006)

作者(Authors): 王金娟;裴学海;杨志翔;王文琛;尹晓刚;陈治明;

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