基于光活化过硫酸盐的高级氧化技术:机理及研究进展Advanced Oxidation Processes Based on Photoactivated Persulfates: Mechanisms and Research Progress
安攀,马天心,鲍剑群,李卡迪,王宇婷,王雅君
摘要(Abstract):
介绍了过硫酸盐的理化性质和反应机制,阐述了紫外光(UV)、紫外光协同耦合过渡金属(UV/TM)、可见光(Vis)、可见光协同耦合过渡金属(Vis/TM)等途径活化过硫酸盐的机理,回顾了相关材料的研究进展。对光活化过硫酸盐高级氧化技术去除环境中有机污染物面临的关键挑战和发展方向,进行了探讨和展望。
关键词(KeyWords): 光活化;过硫酸盐;过渡金属;降解;有机污染物;高级氧化技术
基金项目(Foundation): 国家自然科学基金项目(52270115)
作者(Author): 安攀,马天心,鲍剑群,李卡迪,王宇婷,王雅君
参考文献(References):
- [1]CHENG M,ZENG G,HUANG D,et al.Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds:a review[J].Chemical Engineering Journal,2016,284:582-598.
- [2]WU Z,TONG Z,XIE Y,et al.Efficient degradation of tetracycline by persulfate activation with Fe,Co and O co-doped g-C3N4:performance,mechanism and toxicity[J].Chemical Engineering Journal,2022,434:134732.
- [3]QIAO M,WU X,ZHAO S,et al.Peroxymonosulfate enhanced photocatalytic decomposition of silver-cyanide complexes using g-C3N4 nanosheets with simultaneous recovery of silver[J].Applied Catalysis B:Environmental,2020,265:118587.
- [4]丁春生,郑中弈,朱荣辉,等.热活化过硫酸钠降解饮用水中亚硝基二乙胺[J].福建师范大学学报(自然科学版),2023,39(1):13-20.
- [5]JOHNSON R L,TRATNYEK P G,JOHNSON R O B.Persulfate persistence under thermal activation conditions[J].Environmental Science & Technology,2008,42(24):9350-9356.
- [6]HORI H,NAGANO Y,MURAYAMA M,et al.Efficient decomposition of perfluoroether carboxylic acids in water with a combination of persulfate oxidant and ultrasonic irradiation[J].Journal of Fluorine Chemistry,2012,141:5-10.
- [7]NAIM S,GHAUCH A.Ranitidine abatement in chemically activated persulfate systems:assessment of industrial iron waste for sustainable applications[J].Chemical Engineering Journal,2016,288:276-288.
- [8]SCARIA J,GOPINATH A,RANJITH N,et al.Carbonaceous materials as effective adsorbents and catalysts for the removal of emerging contaminants from water[J].Journal of Cleaner Production,2022,350:131319.
- [9]YU S,GAO C,JI Z,et al.Electron-hole separation and microcell-activated peroxymonosulfate driven by Mo/ZnO/NiF@GO/ZnFe2O4/CC dual electrodes for photocatalytic oxidation degradation of tetracycline hydrochloride[J].Separation and Purification Technology,2024,342:127044.
- [10]LI R,HUANG J,CAI M,et al.Activation of peroxymonosulfate by Fe doped g-C3N4 /graphene under visible light irradiation for Trimethoprim degradation[J].J Hazard Mater,2020,384:121435.
- [11]TSITONAKI A,PETRI B,CRIMI M,et al.In situ chemical oxidation of contaminated soil and groundwater using persulfate:a review[J].Critical Reviews in Environmental Science and Technology,2010,40(1):55-91.
- [12]HORI H,YAMAMOTO A,HAYAKAWA E,et al.Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant[J].Environmental Science & Technology,2005,39(7):2383-2388.
- [13]WANG A,ZHOU P,TIAN D,et al.Enhanced oxidation of fluoroquinolones by visible light-induced peroxydisulfate:the significance of excited triplet state species[J].Applied Catalysis B:Environmental,2022,316:121631.
- [14]YANG J,ZHU M,DIONYSIOU D D.What is the role of light in persulfate-based advanced oxidation for water treatment?[J].Water Research,2021,189:116627.
- [15]MICHALEC K,KUSIOR A.From adsorbent to photocatalyst:the sensitization effect of SnO2 surface towards dye photodecomposition[J].Molecules,2021,26(23):7123.
- [16]ZHANG G,KIM G,CHOI W.Visible light driven photocatalysis mediated via ligand-to-metal charge transfer (LMCT):an alternative approach to solar activation of titania[J].Energy & Environmental Science,2014,7(3):954-966.
- [17]LUO C,MA J,JIANG J,et al.Simulation and comparative study on the oxidation kinetics of atrazine by UV/H2O2,UV/HSO-5 and UV/S2O■[J].Water Research,2015,80:99-108.
- [18]AO X,LIU W,SUN W,et al.Medium pressure UV-activated peroxymonosulfate for ciprofloxacin degradation:Kinetics,mechanism,and genotoxicity[J].Chemical Engineering Journal,2018,345:87-97.
- [19]SHUKLA P,FATIMAH I,WANG S,et al.Photocatalytic generation of sulphate and hydroxyl radicals using zinc oxide under low-power UV to oxidise phenolic contaminants in wastewater[J].Catalysis Today,2010,157(1):410-414.
- [20]AO X,LIU W.Degradation of sulfamethoxazole by medium pressure UV and oxidants:peroxymonosulfate,persulfate,and hydrogen peroxide[J].Chemical Engineering Journal,2017,313:629-637.
- [21]AO X,SUN W,LI S,et al.Degradation of tetracycline by medium pressure UV-activated peroxymonosulfate process:influencing factors,degradation pathways,and toxicity evaluation[J].Chemical Engineering Journal,2019,361:1053-1062.
- [22]KHANDARKHAEVA M,BATOEVA A,ASEEV D,et al.Oxidation of atrazine in aqueous media by solar- enhanced Fenton-like process involving persulfate and ferrous ion[J].Ecotoxicology and Environmental Safety,2017,137:35-41.
- [23]WANG R,YU W,FANG N,et al.Constructing fast charge separation of ZnIn2S4 @CuCo2S4 p-n heterojunction for efficient photocatalytic hydrogen energy recovery from quinolone antibiotic wastewater[J].Applied Catalysis B:Environmental,2024,341:123284.
- [24]HORI H,YAMAMOTO A,KOIKE K,et al.Persulfate-induced photochemical decomposition of a fluorotelomer unsaturated carboxylic acid in water[J].Water Research,2007,41(13):2962-2968.
- [25]YEBER M C,GARCíA G.Photocatalytic degradation of Kraft Lignin using the S2O2- 8/ Fe0/UV process:optimization with multivariate analysis[J].Desalination and Water Treatment,2015,56(7):1793-1801.
- [26]GRACA C A L,VELOSA A C,TEIXEIRA A C S C.Amicarbazone degradation by UVA-activated persulfate in the presence of hydrogen peroxide or Fe2+[J].Catalysis Today,2017,280:80-85.
- [27]CHANG X,LIN T,CHEN W,et al.A new perspective of membrane fouling control by ultraviolet synergic ferrous iron catalytic persulfate (UV/Fe(Ⅱ)/PS) as pretreatment prior to ultrafiltration[J].Science of the Total Environment,2020,737:139711.
- [28]KHAN J A,HE X,KHAN H M,et al.Oxidative degradation of atrazine in aqueous solution by UV/H2O2/Fe2+,UV/S2O■/Fe2+ and UV/HSO-5/Fe2+ processes:a comparative study[J].Chemical Engineering Journal,2013,218:376-383.
- [29]SUN J,SONG M,FENG J,et al.Highly efficient degradation of ofloxacin by UV/Oxone/Co2+ oxidation process[J].Environmental Science and Pollution Research,2012,19(5):1536-1543.
- [30]ANIPSITAKIS G P,DIONYSIOU D D.Transition metal/UV-based advanced oxidation technologies for water decontamination[J].Applied Catalysis B:Environmental,2004,54(3):155-163.
- [31]YANG Q,CHOI H,CHEN Y,et al.Heterogeneous activation of peroxymonosulfate by supported cobalt catalysts for the degradation of 2,4-dichlorophenol in water:the effect of support,cobalt precursor,and UV radiation[J].Applied Catalysis B:Environmental,2008,77(3):300-307.
- [32]DENG X,ZHAO Z,WANG C,et al.Insight into the nonradical mechanism of persulfate activation via visible-light for enhanced degradation of sulfonamides without catalyst[J].Applied Catalysis B:Environmental,2022,316:121653.
- [33]QIN F,ALMATRAFI E,ZHANG C,et al.Catalyst-free photochemical activation of peroxymonosulfate in xanthene-rich systems for Fenton-like synergistic decontamination:efficacy of proton transfer process[J].Angew Chem Int Ed Engl,2023,62(20):e202300256.
- [34]JIA J,LIU D,WANG S,et al.Visible-light-induced activation of peroxymonosulfate by TiO2 nano-tubes arrays for enhanced degradation of bisphenol A[J].Separation and Purification Technology,2020,253:117510.
- [35]HAN Z,DENG Y,FEI J,et al.Facile synthesis of amidoximated PAN fiber-supported TiO2 for visible light driven photocatalysis[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,600:124947.
- [36]QU S,LI C,SUN X,et al.Enhancement of peroxymonosulfate activation and utilization efficiency via iron oxychloride nanosheets in visible light[J].Separation and Purification Technology,2019,224:132-141.
- [37]GAO Y,LI S,LI Y,et al.Accelerated photocatalytic degradation of organic pollutant over metal-organic framework MIL-53(Fe) under visible LED light mediated by persulfate[J].Applied Catalysis B:Environmental,2017,202:165-174.
- [38]WANG A,WANG H,DENG H,et al.Controllable synthesis of mesoporous manganese oxide microsphere efficient for photo-Fenton-like removal of fluoroquinolone antibiotics[J].Applied Catalysis B:Environmental,2019,248:298-308.
- [39]WANG Q,CUI Y,HUANG R,et al.A heterogeneous Fenton reaction system of N-doped TiO2 anchored on sepiolite activates peroxymonosulfate under visible light irradiation[J].Chemical Engineering Journal,2020,383:123142.
- [40]ZHANG J,ZHAO W,LI Z,et al.Visible-light-assisted peroxymonosulfate activation over Fe(Ⅱ)/V(Ⅳ) self-doped FeVO4 nanobelts with enhanced sulfamethoxazole degradation:performance and mechanism[J].Chemical Engineering Journal,2021,403:126384.
- [41]ZENG Y,GUO N,XU X,et al.Degradation of bisphenol a using peroxymonosulfate activated by WO3@MoS2/Ag hollow nanotubes photocatalyst[J].Chemosphere,2019,227:589-597.
- [42]QIAN M,WU X L,LU M,et al.Modulation of charge trapping by island-like single-atom cobalt catalyst for enhanced photo-Fenton-like reaction[J].Advanced Functional Materials,2023,33(12):2208688.
- [43]GUL I,SAYED M,REHMAN F,et al.Unlocking the potential of multifunctional and highly porous Ti3C2/TiO2@Bi2O3-based MXene:synergetic photocatalytic activation of peroxymonosulfate,hydrogen evolution and antimicrobial activity[J].Applied Catalysis B:Environment and Energy,2024,359:124493.